Monte Carlo simulation of evaporation-driven self-assembly in suspensions of colloidal rods
نویسندگان
چکیده
منابع مشابه
Evaporation-driven assembly of colloidal particles.
Colloidal particles absorbed at the interface of a liquid droplet arrange into unique packings during slow evaporation [V.N. Manoharan et al., Science 301, 483 (2003)]. We present a numerical and theoretical analysis of the packing selection problem. The selection of a unique packing arises almost entirely from geometrical constraints during the drying.
متن کاملSmectic filaments in colloidal suspensions of rods.
In supersaturated isotropic mixtures of hard rods, smectic filaments have recently been observed. We propose a model for formation and growth of these filaments similar to the Hoffman-Lauritzen model for polymer crystallization. Filament thickness is determined by a compromise between maximizing the amount of smectic phase formed and minimizing the nucleation barrier for adding new segments to ...
متن کاملColloidal interactions in suspensions of rods.
We report direct measurements of entropic interactions of colloidal spheres in suspensions of rodlike fd bacteriophage. We investigate the influence of sphere size, rod concentration, and ionic strength on these interactions. Although the results compare favorably with a recent calculation, small discrepancies reveal entropic effects due to rod flexibility. At high salt concentrations, the pote...
متن کاملMechanism of nanoparticle formation in self-assembled colloidal templates: population balance model and Monte Carlo simulation.
Modeling the nanoparticle formation mechanism in water-in-oil microemulsion, a self-assembled colloidal template, has been addressed in this paper by two formalisms: the deterministic population balance equation (PBE) model and stochastic Monte Carlo (MC) simulation. These are based on time-scale analysis of elementary events consisting of reactant mass transport, solid solubilization, reaction...
متن کاملDo multilayer crystals nucleate in suspensions of colloidal rods?
We study the isotropic-to-crystal transformation in a mixture of colloidal hard rods and nonabsorbing polymer using computer simulations. We determine the height of the nucleation barrier and find that the critical cluster consists of a single crystalline layer growing laterally for all polymer fugacities considered. At lower supersaturation, the free energy of a single hexagonally packed layer...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Review E
سال: 2016
ISSN: 2470-0045,2470-0053
DOI: 10.1103/physreve.94.062803